Brookhaven National Laboratory scientists have observed an unexpected phenomenon in lithium-ion batteries – the most common type of battery used to power cell phones and electric cars. As a model battery generated electric current, the scientists witnessed the concentration of lithium inside individual nanoparticles reverse at a certain point, instead of constantly increasing.
This discovery, published in the journal Science Advances, is a major step toward improving the battery life of consumer electronics.
Esther Takeuchi, a SUNY distinguished professor at Stony Brook University and a chief scientist in the Energy Sciences Directorate at Brookhaven Lab said, “If you have a cell phone, you likely need to charge its battery every day, due to the limited capacity of the battery’s electrodes. The findings in this study could help develop batteries that charge faster and last longer.”
Inside every lithium-ion battery are particles whose atoms are arranged in a lattice – a periodic structure with gaps between the atoms. When a lithium-ion battery supplies electricity, lithium ions flow into empty sites in the atomic lattice.
This diagram shows the spread of positively charged lithium ions across the custom-built FeF2 nanoparticle. The conversion reaction sweeps rapidly across the surface before proceeding more slowly in a layer-by-layer fashion through the bulk of the particle. Image Credit: Brookhaven National Lab. Click image for the largest view.
Wei Zhang, a scientist at Brookhaven’s Sustainable Energy Technologies Department explained, “Previously, scientists assumed that the concentration of lithium would continuously increase in the lattice. But now, we have seen that this may not be true when the battery’s electrodes are made from nano-sized particles. We observed the lithium concentration within local regions of nanoparticles go up, and then down – it reversed.”
Electrodes are often made from nanoparticles in order to increase a battery’s power density. But scientists have not been able to fully understand how these electrodes function, due to a limited ability to watch them work in action. Now, with a unique combination of experimental tools, the scientists were able to image reactions inside the electrodes in real time.
Feng Wang, the leader of this study and a scientist in Brookhaven’s Sustainable Energy Technologies Department took the explanation further, “Similar to how a sponge soaks up water, we can see the overall level of lithium continuously increase inside the nano-sized particles. But unlike water, lithium may preferentially move out of some areas, creating inconsistent levels of lithium across the lattice.”
The scientists explained that uneven movement of lithium could have lasting, damaging effects because it strains the structure of the active materials in batteries and can lead to fatigue failure.
“Before lithium enters the lattice, its structure is very uniform,” Wang said. “But once lithium goes in, it stretches the lattice, and when lithium goes out, the lattice shrinks. So each time you charge and drain a battery, its active component will be stressed, and its quality will degrade over time. Therefore, it is important to characterize and understand how lithium concentration changes both in space and time.”
In order to make these observations, the scientists combined transmission electron microscopy (TEM) experiments, conducted at the Center for Functional Nanomaterials (CFN), a DOE Office of Science User Facility at Brookhaven Lab, and at Brookhaven’s Condensed Matter Physics and Materials Science Department, with x-ray analyses at the National Synchrotron Light Source (NSLS). NSLS is a DOE Office of Science user facility at Brookhaven that closed in 2014 when its successor, NSLS-II, opened.
Yimei Zhu, co-author of the study and a senior physicist at Brookhaven Lab said, “Wang’s team combined TEM with x-ray techniques. Both methods use a similar approach to analyze the structure of materials, but can provide complementary information. Electrons are sensitive to the local structure, while x-rays can probe a larger volume and enable much better statistics.”
The Brookhaven team also developed a nanoscale model battery that could mimic the function of lithium-ion batteries that would “fit” into a TEM. Computer simulations conducted at the University of Michigan further confirmed the surprising conclusions.
Katsuyo Thornton, a professor of materials science and engineering at the University of Michigan, Ann Arbor, who led the theoretical effort said, “We initially thought that the reversal mechanism was similar to those previously proposed, which stemmed from the interactions between nearby particles. However, it turned out a concentration reversal within a single particle could not be explained by existing theories, but rather, it arises from a different mechanism. Simulations were critical in this work because, without them, we would have made an incorrect conclusion.”
While the study focused on lithium-ion batteries, the scientists say the observed phenomenon may also occur in other high-performance battery chemistries.
Wang said, “Down the road, we plan to use the world-class facilities at CFN and NSLS-II to more closely examine how battery materials work, and to find solutions for building new batteries that can charge faster and last longer. These facilities offer the ideal tools for imaging the structure of battery materials in real time and under real-world conditions.”
It sure looks like some taxpayer money is paying off here. Portability of devices is just getting going and miniaturization is going to bring more tools and conveniences to us. Better batteries will get them here sooner and more powerful even faster.
