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Graphene Pushes Skyrmions Closer to Data Storage Reality

This year marks the 30th anniversary of when Albert Fert of France and Peter Grünberg of Switzerland independently discovered that layering materials a particular way created a phenomenon that became known as…

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Graphene Pushes Skyrmions Closer to Data Storage Reality
Graphene Pushes Skyrmions Closer to Data Storage Reality

From the Lithium News archive. This article dates from Jun 2, 2018 and is preserved as first published.

This year marks the 30th anniversary of when Albert Fert of France and Peter Grünberg of Switzerland independently discovered that layering materials a particular way created a phenomenon that became known as giant magnetoresistance (GMR). GMR has always been an opening to the world we now call “spintronics,” in which the spin of electrons, rather than the charge, is used to encode information.

One of the most visible and ubiquitous results of GMR’s discovery is that smartphones are now equipped with a GMR-based hard-disk drive that can hold thousands of photos, videos, and songs. In other words, GMR’s discovery has transformed our lives.

Now, an international team of researchers from the United States and Europe—with the European contingent including Fert once again—has found a new material phenomenon when layering graphene with magnetic materials that could lead to a new era in spintronics that the researchers have dubbed “spin-orbitronics.”

In research described in the journal Nature Materials, scientists from the U.S. Department of Energy’s Lawrence Berkeley National Laboratory and France’s Alternative Energies and Atomic Energy Commission have discovered that when a graphene coating is added to magnetic materials, like cobalt or nickel, the combination of electronic and magnetic properties creates the essential ingredient for triggering swirling patterns at the interface of where these materials meet.

These swirling patterns are known as skyrmions and, for the last five years, have been considered a potential way for storing and erasing data on magnetic media. The prospects of skyrmions as a data storage medium got a boost earlier this year when another group of researchers demonstrated for the first time that a single skyrmion could be electrically detected at room temperature.

These swirling patterns are known as skyrmions and, for the last five years, have been considered a potential way for storing and erasing data on magnetic media.

In order to create these skyrmions, you need a very strong interaction between the electrons of the layered materials. These interactions are known as Dzyaloshinskii–Moriya interactions (DMIs). These DMIs typically occur at the interface between a magnetic film and a heavy metal. The DMI mechanism involves the electrons of the heavy metal interacting with the spins of the atoms in the magnetic layer, and that have spin-orbit coupling with the heavy metal sites. This is where we get the researchers’ “spin-orbitronics” term.

In this latest research, the scientists discovered that they didn’t need a heavy metal layered with magnetic films to create the DMI effect, but that graphene could do the trick. In fact, graphene—which had been considered a poor candidate for producing this DMI effect because it’s a weak spin-orbit coupling material—produced a DMI effect so large it could change the chirality—clockwise or counter-clockwise direction—of the electrons.

“Our work opens up an additional route towards the observation of skyrmions in graphene-based materials which have been of significant interest for graphene spintronics,” said Mairbek Chshiev, professor at Université Grenoble Alpes, and co-author of the research. “We have demonstrated that ferromagnetic/graphene structures provide a large DMI, which is an essential ingredient for skyrmions.”

This large DMI in the ferromagnetic/graphene material means that it is capable of changing the electron spin direction (or chirality) of the magnetic material so completely that the entire material could have its chirality switched in one direction and then another in a very controlled way, offering a method for duplicating the “0” and “1” of digital logic.

This discovery still leaves us far from a real-world device that could exploit the phenomenon for data storage. “To make a real device, there are a lot of things to do in future,” said Hongxin Yang, a co-author of the paper and senior technologist with Avalanche Technology Inc. in San Francisco.

In addition to DMI, Yang believes that a future device will also need perpendicular magnetic anisotropy, which means the magnetization orientation has a preferred direction, in this case a perpendicular one. Yang added that the device may also need tunnel magnetoresistance to read the information—magnetic tunnel junctions form the backbone of read heads in GMR hard-disk drives.

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Minnesota utilities hope surge of big-scale batteries helps transition to clean energyJared Newton remembers panicking at times when launching three first-of-their-kind battery projects in Minnesota for Connexus Energy in 2019. Would lithium technology — paired with solar farms — charge fast enough in the morning to meet afternoon electric needs? "Until I saw it in action, we didn't know if we'd be able to get them charged in time," said Newton, who leads engineering and system operations for the electric cooperative in Ramsey. Newton and Connexus are local trailblazers in the fledgling world of utility batteries. Now, Minnesota is on the brink of a large-scale rollout of the mega batteries over the next six years, putting the state on pace for a relative boom in battery infrastructure. On Thursday, state utility regulators approved a certificate of need for a $450 million project by Invenergy near Lake Wilson that would be by far the largest storage system in the state. Utilities — plus state planners here and across the country — are counting on utility-scale batteries to help with the shift from coal to wind and solar energy in the next two decades. However, many forms of the promising technology are still mostly untested beyond pilot projects and the batteries, while they have dropped in price, are still expensive. Xcel Energy, Minnesota's largest electricity provider, has no batteries in the state so far but released plans in February for a sizable fleet to help as it works toward closing its coal plants by 2030. A study commissioned by the state Legislature released this month also said a battery influx is needed for utilities to meet a state target for carbon-free electricity by 2040. "I feel like we've been talking about [energy storage] a long time," said Julie Pierce, vice president of planning and strategy for Duluth-based Minnesota Power. "Now we're really seeing the fit and form come into fruition here." What batteries can be used for The biggest challenge of shifting energy sources from fossil fuels to wind and solar power is 24-hour reliability. If there's no wind or it's a cloudy day, it can interfere with power generation. Especially during spikes in need, utilities need a backup. Xcel has two large nuclear plants, some hydropower and will use natural gas "peaking" plants for many years. But batteries can be used instead of gas for extra juice when demand is at its highest, like a hot summer day when people are running air-conditioning. "We're losing over two gigawatts of round-the-clock potential baseload power," said Justin Tomljanovic, Xcel's vice president of corporate development. "We're replacing it with generally intermittent resources." Two gigawatts can supply enough power for up to 2 million homes. Astrid Atkinson, CEO of California-based Camus Energy, said batteries also will play many smaller and more specific roles in a modern electric grid that has become more complex because of things like increased use of electric vehicles. Her company is working with Connexus and pitches software that acts as an air-traffic controller and helps cooperatives better use batteries. Pilot projects and 'baby steps' Connexus has 15 megawatts of batteries at three sites and plans for more. It uses a form of common lithium batteries that has a short battery life but is trusted and already widely available. Not only was the cooperative an early adopter of batteries, it still stands out. Outside of Connexus, there was only one other utility-scale battery facility in Minnesota as of December, a state study released this month found, and it is small. The study, commissioned by the Legislature and conducted by Siemens Industry, suggested Minnesota could need between 1.35 and 2.8 gigawatts of energy storage to hit the 2040 carbon-free target. Siemens pegged the optimal amount at 1.7 gigawatts, a little more than the capacity of Xcel's largest Minnesota coal plant in Sherburne County. So far, Xcel has state approval for an experimental 10 megawatt, 100-hour long-duration battery with Form Energy that uses iron and the process of rusting to store power. Great River Energy has a smaller pilot project with Form in the works, too. Cole Funseth, Great River's manager of generation engineering, said the battery is so promising and desired by the industry because it could help over long stretches, like a polar vortex that hampers natural gas production. Minnesota Power is a partner on the state's other battery facility, a small lithium ion project in Grand Rapids, but the company is eyeing grant funding after unsuccessfully applying for federal help to test another long-lasting technology known as a flow battery. "The utilities are still very much calling these pilot projects," said Beth Soholt, executive director of Clean Grid Alliance, a trade group that represents wind, solar and battery developers. "Until they have operating experience — they can touch it, kick it, see what it does — they don't know." Meanwhile, Soholt said the 15-state regional grid operator is still taking "baby steps" on batteries, writing rules for the open energy market that will be critical for developers and the future of the technology. In this early phase, utilities also say grant money is crucial. Ryan Long, Xcel's president in Minnesota, said in general the economics for batteries have improved. But Pierce of Minnesota Power said costs are still high, especially for technology that hasn't been fully commercialized. "It's probably on the higher end of some of the [carbon-free] alternatives right now, though we do have a lot of hope for the industry," Pierce said. Xcel, while refusing to divulge the overall cost, got a $70 million grant to use on the Form pilot project in Minnesota and another in Colorado, as well as $20 million from a Bill Gates-founded platform. Power surge ahead Xcel's new long-range plan calls for 600 megawatts of storage by 2030, which is large but less than half the power output of the large coal-fired plant in Sherburne County. Great River plans to add 200 megawatts in 2030. The state Public Utilities Commission (PUC) approved a plan for Minnesota Power to incorporate up to 500 megawatt hours — a measure that accounts for output and duration — of storage, likely by 2030. That is in the ballpark for how much battery storage Siemens found each utility might need. Smaller cooperatives and municipal utilities also will have to build hundreds of megawatts of batteries in total, Siemens said. Still, the question of exactly what kind of technology the utilities will build is unresolved. Connexus seems likely to keep its focus on lithium, the proverbial meat and potatoes of the battery world. Newton said long-duration batteries are likely critical in a carbon-free grid, but he said the highly anticipated technology such as Form seems "sort of like vaporware" until it's actually operating. Xcel isn't solely focused on the Form battery either. Tomljanovic said the utility is planning on also using lots of the readily available lithium ion units. And because long-range technology is still under development, the Siemens projection was based on four-hour lithium ion. Great River initially said its Form battery would be in operation by the end of 2023, though now the company expects late 2024 or early 2025. Funseth said the delay is because GRE is waiting to get batteries produced at Form's factory under construction in West Virginia rather than get custom infrastructure. "I wish the Form Energy pilot projects could go faster," Soholt said. "Because I think that we need to understand if they're going to pan out or not." Minnesota Power also is looking at a combination of technologies, Pierce said. The utility needs energy storage systems that can last for 10 to 12 hours that would better serve the company's customer base, which includes heavy industry like taconite mines. Right now, along with state regulators, Xcel is taking bids for a large amount of what is called "dispatchable" energy — power sources like gas plants or batteries that can be called on quickly for fast power that isn't dependent on weather. The Invenergy project near Lake Wilson in front of the PUC Thursday was for a 95 MW lithium ion battery project — the largest in the state if built — and solar farm. Then there are more novel ideas. California-based Rondo Energy bid what it calls a thermal battery, which would operate by storing heat in refractory bricks that could be released as steam heat or electricity. Connexus, Newton said, is confident now in both the economics and operation of its batteries. "It had to save money for the members," he said. "But then we're also really excited because we now have had a team of engineers and operators that have five years of battery experience under their belt."